In an article, published in an article, once mentioned the application of 4175-76-2, Name is 2,4-Dichlorothiazole,molecular formula is C3HCl2NS, is a conventional compound. this article was the specific content is as follows.name: 2,4-Dichlorothiazole
Herein, conditions for C-H functionalization of tertiary aliphatic amines and their subsequent coupling with a number of 2-chloroazole derivatives are reported. The reaction is facilitated by a catalytic amount of tris-fac-Ir(ppy)3, with blue light irradiation and takes place under mild and convenient conditions. Most couplings take place with excellent regioselectivity. The reaction is tolerant of a number of functional groups and allows for rapid access to alpha-azole carbinamines commonly found in post-translationally modified peptides.
Herein, conditions for C-H functionalization of tertiary aliphatic amines and their subsequent coupling with a number of 2-chloroazole derivatives are reported. The reaction is facilitated by a catalytic amount of tris-fac-Ir(ppy)3, with blue light irradiation and takes place under mild and convenient conditions. Most couplings take place with excellent regioselectivity. The reaction is tolerant of a number of functional groups and allows for rapid access to alpha-azole carbinamines commonly found in post-translationally modified peptides.
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Reference£º
Thiazole | C3H1503NS – PubChem,
Thiazole | chemical compound | Britannica