The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 76824-35-6, Name is Famotidine, SMILES is N=C(NS(=O)(N)=O)CCSCC1=CSC(NC(N)=N)=N1, in an article , author is Newman, Ben, once mentioned of 76824-35-6, HPLC of Formula: C8H15N7O2S3.
Water-Soluble Iridium(III) Complexes Containing Tetraethylene-Glycol-Derivatized Bipyridine Ligands for Electrogenerated Chemiluminescence Detection
Four cationic heteroleptic iridium(III) complexes containing a 2,2 ‘-bipyridine (bpy) ligand with one or two tetraethylene glycol (TEG) groups attached in the 4 or 4,4 ‘ positions were synthesized to create new water-soluble electrogenerated chemiluminescence (ECL) luminophores bearing a convenient point of attachment for the development of ECL-labels. The novel TEG-derivatized bipyridines were incorporated into [Ir((CN)-N-perpendicular to)(2)(R-bpy-R ‘)]Cl complexes, where (CN)-N-perpendicular to = 2-phenylpyridine anion (ppy) or 2-phenylbenzo[d]thiazole anion (bt), through reaction with commercially available ([Ir((CN)-N-perpendicular to)(2)(mu-Cl)](2) dimers. The novel [Ir((CN)-N-perpendicular to)(2)(Me-bpy-TEG)]Cl and [Ir((CN)-N-perpendicular to)(2)(TEG-bpy-TEG)]Cl complexes in aqueous solution largely retained the redox potentials and emission spectra of the parent [Ir((CN)-N-perpendicular to)(2)(Me-bpy-Me)]PF6 (where Me-bpy-Me = 4,4 ‘ methyl-2,2 ‘-bipyridine) luminophores in acetonitrile, and exhibited ECL intensities similar to those of [Ru(bpy)(3)](2+) and the analogous [Ir((CN)-N-perpendicular to)(2)(pt-TEG]Cl complexes (where pt-TEG = 1-(TEG)-4-(2-pyridyl)-1,2,3-triazole). These complexes can be readily adapted for bioconjugation and considering the spectral distributions of [Ir(ppy)(2)(Me-bpy-TEG)](+) and [Ir(ppy)(2)(pt-TEG)](+), show a viable strategy to create ECL-labels with different emission colors from the same commercial [Ir(ppy)(2)(mu-Cl)](2) precursor.
Interested yet? Read on for other articles about 76824-35-6, you can contact me at any time and look forward to more communication. HPLC of Formula: C8H15N7O2S3.
Reference:
Thiazole | C3H3NS – PubChem,
,Thiazole | chemical compound | Britannica