Electric Literature of 81569-44-0, An article , which mentions 81569-44-0, molecular formula is C6H7NO2S. The compound – Methyl 4-methylthiazole-5-carboxylate played an important role in people’s production and life.
The first example of cobalt-catalyzed oxidative C?H/C?H cross-coupling between two heteroarenes is reported, which exhibits a broad substrate scope and a high tolerance level for sensitive functional groups. When the amount of Co(OAc)2?4 H2O is reduced from 6.0 to 0.5 mol %, an excellent yield is still obtained at an elevated temperature with a prolonged reaction time. The method can be extended to the reaction between an arene and a heteroarene. It is worth noting that the Ag2CO3oxidant is renewable. Preliminary mechanistic studies by radical trapping experiments, hydrogen/deuterium exchange experiments, kinetic isotope effect, electron paramagnetic resonance (EPR), and high resolution mass spectrometry (HRMS) suggest that a single electron transfer (SET) pathway is operative, which is distinctly different from the dual C?H bond activation pathway that the well-described oxidative C?H/C?H cross-coupling reactions between two heteroarenes typically undergo.
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Reference£º
Thiazole | C3H8479NS – PubChem,
Thiazole | chemical compound | Britannica