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REACTIONS OF 2-TRIMETHYLSILYLYHIAZOLE WITH ACYL CHLORIDES AND ALDEHYDES SYNTHESIS OF NEW THIAZOL-2-YL DERIVATES
2-Trimethylsilylthiazole (1) undergoes ipso-substitution of the silyl group with various acyl chlorides and ethyl chloroformate affording 2-acylthiazoles (2)-(5) but adds by the carbon-silicon bond to the carbonyl group of aldehydes yielding thiazol-2-yl-trimethylsiloxy-methane derivates (7).
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Reference：
Thiazole | C3H1154NS – PubChem,
Thiazole | chemical compound | Britannica