7709-58-2, Name is 4-(Chloromethyl)thiazole hydrochloride, molecular formula is C4H5Cl2NS, belongs to thiazole compound, is a common compound. In a patnet, once mentioned the new application about 7709-58-2, Product Details of 7709-58-2
Four N,O-bidentate chelating ligands [L1=N-(4-thiazolylmethyl)morpholine-N-oxide, L2=N-(2-pyridylmethyl)pyrrolidine-N-oxide, L3=N-(4-thiazolylmethyl)pyrrolidine-N-oxide, and L4=N-(2-pyridylmethyl)morpholine-N-oxide] were designed and synthesized. The treatment of N,O-bidentate ligands with CuCl2 in ethanol at room temperature afforded four new copper complexes?[Cu(L1)2]Cl2 (I), [Cu(L2)2][CuCl4] (II), [Cu(L3)2Cl]2[CuCl2(H2O)2]Cl2?10 H2O (III) and [Cu(L4)2][Cu(L4)2(CH3OH)2][CuCl4]2 (IV)?which were fully characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analyses. Most interestingly, the single-crystal X-ray diffraction analyses revealed that the N,O-bidentate ligands L1?L4 can tune the corresponding geometry configuration of copper atoms in complexes I?IV. The copper atoms in I and II showed four-coordinated distorted square planar geometry, whereas the central copper atom in III adopted a distorted square pyramidal geometry. It should be noted that complex IV was constructed by a distorted square planar CuN2O2 unit, one octahedral CuN2O4 unit and two [CuCl4]2? anions. Importantly, these copper(II) complexes, especially complex IV, showed high catalytic activity in Chan?Lam coupling reactions of primary or secondary amines with arylboronic acid under mild conditions. Substrates with many functional groups were tolerated and the C?N coupling products were afforded in good to excellent yields (up to 96 % yield).
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 7709-58-2. In my other articles, you can also check out more blogs about 7709-58-2
Reference：
Thiazole | C3H4766NS – PubChem,
Thiazole | chemical compound | Britannica