79265-30-8, Name is 2-(Trimethylsilyl)thiazole, molecular formula is C6H11NSSi, belongs to thiazole compound, is a common compound. In a patnet, once mentioned the new application about 79265-30-8, Recommanded Product: 2-(Trimethylsilyl)thiazole
Diastereocontrolled Lewis acid-catalyzed preparation of enantiopure carbacepham derivatives have been developed starting from 2-azetidinone-tethered enals. The BF3.Et2O-promoted reaction of alkenylaldehydes 1 and 16 is effective as carbocyclization protocol to afford 4-substituted 5-hydroxycarbacephams or 3-substituted 4,5-dihydroxycarbacephams, respectively, by a type I carbonyl-ene reaction, while the BF3. Et2O or SnCl4-mediated type II carbonyl-ene cyclization of alkenylaldehydes 2 furnishes 3-methylene 5-hydroxycarbacephams along with the corresponding 3-halo 5-hydroxycarbacepham. The stereochemical outcome of these carbonyl-ene cyclizations leading to carbacepham derivatives can be explained in terms of six-membered, cyclic chair-like transition-state models. The formation of halocarbacepham derivatives is proposed to proceed by a stepwise mechanism.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: 2-(Trimethylsilyl)thiazole. In my other articles, you can also check out more blogs about 79265-30-8
Reference：
Thiazole | C3H1110NS – PubChem,
Thiazole | chemical compound | Britannica