Application of 13838-78-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 13838-78-3, Name is 5-Methylthiazole-2-carbaldehyde. In a document type is Article, introducing its new discovery.
Stereoselective synthesis of exocyclic enones 10?17 via a base-catalyzed direct aldol condensation between dihydrolevoglucosenone 1 and heterocyclic aldehydes 2?9 is described. The reaction is performed under mild conditions and is applicable to variety of heterocyclic aldehydes. E-Steroisomers of exo-cyclic enones are the only products. They are very easy to isolate and were formed in good to excellent (72?88%) yield. 1H NMR, 13C NMR analyses provide the structural assignment and absolute stereochemistry of the condensation products. Single-crystal X-ray diffraction of condensation product 12, additionally supports the structural assignment.
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Reference：
Thiazole | C3H6496NS – PubChem,
Thiazole | chemical compound | Britannica