Synthetic Route of C10H24N2. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: N1,N1,N6,N6-Tetramethylhexane-1,6-diamine, is researched, Molecular C10H24N2, CAS is 111-18-2, about One-dimensional intergrowths in two-dimensional zeolite nanosheets and their effect on ultra-selective transport. Author is Kumar, Prashant; Kim, Dae Woo; Rangnekar, Neel; Xu, Hao; Fetisov, Evgenii O.; Ghosh, Supriya; Zhang, Han; Xiao, Qiang; Shete, Meera; Siepmann, J. Ilja; Dumitrica, Traian; McCool, Benjamin; Tsapatsis, Michael; Mkhoyan, K. Andre.
Zeolite MFI is a widely used catalyst and adsorbent that also holds promise as a thin-film membrane. The discovery of nanometer-thick two-dimensional (2D) MFI nanosheets has facilitated methods for thin-film zeolite fabrication that open new horizons for membrane science and engineering. However, the crystal structure of 2D-MFI nanosheets and their relationship to separation performance remain elusive. Using transmission electron microscopy, we find that one- to few-unit-cell-wide intergrowths of zeolite MEL exist within 2D-MFI. We identify the planar distribution of these 1D or near-1D-MEL domains, and show that a fraction of nanosheets have high (∼25% by volume) MEL content while the majority of nanosheets are MEL-free. Atomistic simulations show that commensurate knitting of 1D-MEL within 2D-MFI creates more rigid and highly selective pores compared to pristine MFI nanosheets, and permeation experiments show a separation factor of 60 using an industrially relevant (undiluted 1 bar xylene mixture) feed. Confined growth in graphite is shown to increase the MEL content in MFI nanosheets. Our observation of these intergrowths suggests strategies for the development of ultra-selective zeolite membranes.
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Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica