Application In Synthesis of 2,6-Dimethyl-3,5-heptanedione. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 2,6-Dimethyl-3,5-heptanedione, is researched, Molecular C9H16O2, CAS is 18362-64-6, about Highly efficient enantio-differentiating hydrogenation over an ultrasonicated Raney nickel catalyst modified with tartaric acid. Author is Tai, Akira; Kikukawa, Tadashi; Sugimura, Takashi; Inoue, Yosihisa; Osawa, Tsutomu; Fujii, Satoshi.
A tartaric acid-NaBr-modified ultrasonicated Raney nickel catalyst showed enantioselective activity in the hydrogenation of 1,3-diketones and Me 3-oxoalkanonates. Hydrogenation of MeCOCH2COMe with ultrasonicated, modified Raney nickel gave (R)-MeCH(OH)CH2COMe, meso-MeCH(OH)CH2C(OH)Me, and erythro-MeCH(OH)CH2C(OH)Me in a 7:7:86 ratio; the yield of erythro-MeCH(OH)CH2CH(OH)Me (32% enantiomeric excess) was 60%. Reduction of MeCOCH2CO2Me gave (R)-MeCH(OH)CH2CO2Me in 86% enantiomeric excess.
There is still a lot of research devoted to this compound(SMILES：CC(C)C(CC(C(C)C)=O)=O)Application In Synthesis of 2,6-Dimethyl-3,5-heptanedione, and with the development of science, more effects of this compound(18362-64-6) can be discovered.
Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica