Reference of 2,6-Dimethyl-3,5-heptanedione. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 2,6-Dimethyl-3,5-heptanedione, is researched, Molecular C9H16O2, CAS is 18362-64-6, about FeCl3-catalyzed selective acylation of amines with 1,3-diketones via C-C bond cleavage. Author is Wang, Sinan; Yu, Yang; Chen, Xuyun; Zhu, Haipan; Du, Peile; Liu, Guohua; Lou, Liguang; Li, Hao; Wang, Wei.
We describe a novel FeCl3 catalyzed selective acylation of amines involving the C-C bond cleavage of simple 1,3-diketones. The process proceeds efficiently under a neat condition to give structurally diverse amides. Notably, the acylation process displays high selectivity toward amines over hydroxyl functionality. Traditionally difficult aromatic amines and sterically demanding disubstituted amines can engage in the process with high efficiency.
There is still a lot of research devoted to this compound(SMILES：CC(C)C(CC(C(C)C)=O)=O)Reference of 2,6-Dimethyl-3,5-heptanedione, and with the development of science, more effects of this compound(18362-64-6) can be discovered.
Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica