Electric Literature of C35H27N2O2Ir. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Bis[2-(1-isoquinolinyl-N)phenyl-C](2,4-pentanedionato-O2,O4)iridium(III), is researched, Molecular C35H27N2O2Ir, CAS is 435294-03-4, about Determination of emitting dipole orientation in organic light emitting diodes. Author is Jiang, Nan; Yang, Han-Nan; Man, Jia-Xiu; Zhang, Tao; He, Shou-Jie; Wang, Deng-Ke; Lu, Zheng-Hong.
The dipole orientation of a light-emitting mol. dictates the external quantum efficiency (EQE) of an organic light emitting diode (OLED). In this paper, we studied both exptl. and theor. relationships between dipole orientation and measurable optical properties of working OLEDs. Theor. electroluminescence (EL) spectrum, EQE, and luminance angle distribution are simulated by incorporating the dipole radiation pattern into Fabry- Perot cavity theory with horizontal dipole ratio as a variable parameter. The horizontal ratio is determined by optimizing the fitness of theor. EL spectra to the exptl. data and EL angular distribution. We show that the optical model proposed in this paper describes well the emission dipole dependent device optical data including EL spectra, EQEs, and EL luminance angular distributions. The emission fill factor (EFF), defined as the area ratio of EL angular distribution to the Lambertian curve, is found to follow a linear relationship with horizontal dipole ratio. These results provide a simple guide to deduce dipole orientations in working OLEDs.
In addition to the literature in the link below, there is a lot of literature about this compound(Bis[2-(1-isoquinolinyl-N)phenyl-C](2,4-pentanedionato-O2,O4)iridium(III))Electric Literature of C35H27N2O2Ir, illustrating the importance and wide applicability of this compound(435294-03-4).
Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica