Synthetic Route of C35H27N2O2Ir. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Bis[2-(1-isoquinolinyl-N)phenyl-C](2,4-pentanedionato-O2,O4)iridium(III), is researched, Molecular C35H27N2O2Ir, CAS is 435294-03-4, about White light emission produced by CTMA-DNA nanolayers embedded with a mixture of organic light-emitting molecules. Author is Chopade, Prathamesh; Dugasani, Sreekantha Reddy; Jeon, Sohee; Jeong, Jun-Ho; Park, Sung Ha.
In this regard, DNA can be utilized as a competent scaffold for hosting functional nanomaterials to develop a designated platform in the field of bionanotechnol. Here, we introduce a novel methodol. to construct CTMA-modified DNA nanolayers (CDNA NLs) embedded with single (e.g., red, green, and blue), double (violet, yellow, and orange), and triple (white) iridium-based organic light-emitting materials (OLEMs, including Ir(piq)2(acac) for red, Ir(ppy)2(acac) for green, FIrpic for blue) that can serve as active light-emitting layers. The OLEM-embedded CDNA NLs were fabricated using simple solution processes, and their spectral properties were investigated via Fourier-transform IR (FTIR), X-ray photoelectron (XPS), UV-Vis, and photoluminescence (PL) spectroscopies. FTIR anal. of OLEM-embedded CDNA NLs suggested that the complexes are stable and chem. inert. The wide band gap characteristics (~4.76 eV) and relatively high optical quality (no absorption in the visible region) of OLEM-embedded CDNA NLs were observed in UV-Vis absorption measurements. We observed PL emission in OLEM-embedded CDNA NLs, which was caused by the energy transfer from CDNA to OLEMs (ligand-centered and metal to ligand charge transfer). Lastly, a white light-emitting OLEM-embedded CDNA thin film was constructed using a combination of appropriate concentrations of red, green, and blue OLEMs.
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Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica