Huang, Garrett; Mandal, Mrinmay; Hassan, Noor Ul; Groenhout, Katelyn; Dobbs, Alexandra; Mustain, William E.; Kohl, Paul A. published the article 《Ionomer optimization for water uptake and swelling in anion exchange membrane electrolyzer: hydrogen evolution electrode》. Keywords: anion exchange membrane electrolyzer hydrogen evolution electrode.They researched the compound: N1,N1,N6,N6-Tetramethylhexane-1,6-diamine( cas:111-18-2 ).Computed Properties of C10H24N2. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:111-18-2) here.
Green hydrogen produced through anion exchange membrane water electrolysis is a promising, low-cost chem. storage solution for intermittent renewable energy sources. Low-temperature electrolysis using anion exchange membranes (AEM) combines the benefits of established water electrolysis technologies based on alk. electrolysis and proton exchange membrane electrolysis. The anion conductive ionomers (ACI) used in the AEM electrolyzer (AEMEL) electrodes has been investigated. The ACI serves two primary purposes: (i) facilitate hydroxide conduction between the catalyst and bulk electrolyte and (ii) bind the catalyst to the porous transport layer and membrane. High ion exchange capacity (IEC) ACIs are desired, however, high IEC can cause excessive water uptake (WU) and detrimental ACI swelling. Proper water management is a key factor in obtaining maximum performance in AEM-based devices. In this study, a series of poly(norbornene)-based ACIs were synthesized and deployed in hydrogen evolving AEMEL cathode electrodes. A balance between ionic conductivity, WU and ionomer swelling was achieved in the ACI by varying the IEC and degree of polymer crosslinking. It was found that higher IEC ACIs with light crosslinking are preferred in the HER electrode. Such a configuration fine-tuned the WU and ionomer swelling to achieve optimum cell performance and reduce cell operating voltages.
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Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica