Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 92-71-7, is researched, SMILESS is C1(C2=CC=CC=C2)=NC=C(C3=CC=CC=C3)O1, Molecular C15H11NOJournal, Article, JACS Au called Chiral Hypervalent Iodine Catalysis Enables an Unusual Regiodivergent Intermolecular Olefin Aminooxygenation, Author is Wu, Fan; Kaur, Navdeep; Alom, Nur-E.; Li, Wei, the main research direction is oxazoline preparation regioselective; alkene amide intermol aminooxygenation iodine catalyst.Application In Synthesis of 2,5-Diphenyloxazole.
A novel iodide-catalyzed intermol. aminooxygenation strategy was described here. Amide was used as the O- and N- source to probe for regiocontrol strategies. Notably, simple additives could be selectively introduced to achieve regiodivergent oxyamination processes for electronically activated alkenes while being regio-complementary for unactivated alkenes. Our preliminary data demonstrates that this regiocontrol strategy based on nucleophile could also be applied in asym. processes using chiral hypervalent iodine catalysis.
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Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica