So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Han, Xiaoqing; Widenhoefer, Ross A. researched the compound: 2,6-Dimethyl-3,5-heptanedione( cas:18362-64-6 ).Application of 18362-64-6.They published the article 《Palladium-catalyzed oxidative alkoxylation of α-alkenyl β-diketones to form functionalized furans》 about this compound( cas:18362-64-6 ) in Journal of Organic Chemistry. Keywords: alkenylalkanedione oxidative alkoxylation; furan preparation; palladium oxidative alkoxylation catalyst. We’ll tell you more about this compound (cas:18362-64-6).
Treatment of 4-allyl-2,6-dimethyl-3,5-heptanedione (I) with a catalytic amount of PdCl2(CH3CN)2, and a stoichiometric amount of CuCl2, provided 3-isobutyryl-2-isopropyl-5-methylfuran (II) in good yield. A series of α-alkenyl β-diketones underwent oxidative alkoxylation, under these conditions, to give 2,3,5-trisubstituted furans in moderate to good yields.
After consulting a lot of data, we found that this compound(18362-64-6)Application of 18362-64-6 can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica