Name: 6-Nitrobenzo[d]thiazol-2-amineIn 2022, Sheetal;Sengupta, Sirsendu;Singh, Manjeet;Thakur, Sanjeeve;Pani, Balaram;Banerjee, Priyabrata;Kaya, Savas;Singh, Ashish Kumar published 《An insight about the interaction of Aryl Benzothiazoles with mild steel surface in aqueous HCl solution》. 《Journal of Molecular Liquids》published the findings. The article contains the following contents:
The arrival of organic moieties as corrosion inhibitors has expanded the research in the past few years which, as a result; involved different heteroatoms to be tested for their anti-corrosive potential. The presented research is focused on the synthesis of the aryl-substituted benzothiazoles namely 6-(4-Chlorophenyl) benzo[d]thiazol-2-amine (CBTA), 6-(p-tolyl) benzo[d]thiazol-2-amine (TBTA), and 6-(4-methoxyphenyl) benzo[d]thiazol-2-amine (MBTA), and investigation of their anti-corrosive behavior on mild steel in 1 M HCl particularly. Here, gravimetric and electrochem. analyses have been employed to examine the tendency of benzothiazoles to safeguard mild steel. Corrosion impeding efficacies were found to follow a significant order; MBTA > TBTA > CBTA. Further, exptl. anal. unveiled the effect of substituents on corrosion mitigating potential i.e., MBTA employed the ligation of methoxy group; an enhanced electron cloud thus providing a maximum shield. The addition of corrosion inhibitors in acidic solution brought an elevation in activation energy thus retarded the rate of corrosion. Surface anal. via at. force microscopy (AFM) and XPS confirmed the exptl. results and attributed the presence of an adsorbed layer over mild steel surface thus providing protection from corrosion. Addnl., Quantum calculations such as d. functional theory (DFT) and mol. dynamics (MD) provided an insight into the adsorption of inhibitors over mild steel at a mol. level. The experimental procedure involved many compounds, such as 6-Nitrobenzo[d]thiazol-2-amine (cas: 6285-57-0) .
6-Nitrobenzo[d]thiazol-2-amine(cas:6285-57-0 Name: 6-Nitrobenzo[d]thiazol-2-amine) inhibits the activity of amines, which are small molecules found in many pharmaceuticals. The chemical structure of this drug contains one or more methylene groups that can be activated by diazonium salt to form an intermediate molecule with a reactive amine group.
Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica