Baiget, Jessica; Cosp, Annabel; Galvez, Erik; Gomez-Pinal, Loreto; Romea, Pedro; Urpi, Felix published the artcile< On the influence of chiral auxiliaries in the stereoselective cross-coupling reactions of titanium enolates and acetals>, Computed Properties of 171877-39-7, the main research area is acylthiazolidinethione titanium enolate coupling acetal.
Titanium enolates from chiral N-propanoyl-1,3-thiazolidine-2-thiones containing bulky substituents at C-4 turned out to be excellent platforms to get highly stereocontrolled cross-coupling reactions with acetals. Related oxazolidinethiones also afforded good results, but the corresponding oxazolidinones were completely unselective for such reactions, which proves that an exocyclic C=S bond is essential to attain a synthetically useful stereocontrol.
Tetrahedron published new progress about Acetals Role: RCT (Reactant), RACT (Reactant or Reagent). 171877-39-7 belongs to class thiazole, and the molecular formula is C10H11NS2, Computed Properties of 171877-39-7.
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica