In 2013,New Journal of Chemistry included an article by Zhou, Xiaojing; Zhang, Zhijuan; Li, Baiyan; Yang, Fen; Peng, Yu; Li, Guanghua; Shi, Zhan; Feng, Shouhua; Li, Jing. Electric Literature of C10H8N2O2S. The article was titled 《Two three-dimensional metal-organic frameworks constructed by thiazole-spaced pyridinecarboxylates exhibiting selective gas sorption or antiferromagnetic coupling》. The information in the text is summarized as follows:
The ligand of 2-(4-pyridyl)-4-methylthiazole-5-carboxylic acid (HL) was employed to react with Cd(NO3)2·6H2O or a 50% aqueous solution of Mn(NO3)2, to yield two isomorphous three-dimensional (3D) coordination compounds, [Cd(L)2](H2O)4(DMF) (1) and [Mn(L)2](H2O)3(DMF) (2). The structures and properties of the compounds were characterized by several techniques. Both compounds are three-dimensional (3D) neutral frameworks possessing permanent pores that give rise to straight 1-dimensional channels. Compound 1 displays adsorption selectivity for CO2, while the low pressure sorption of H2, N2, CH4, CO, O2 at 298 K are negligible; Compound 2 shows weak anti-ferromagnetic coupling between the magnetic centers. After reading the article, we found that the author used 4-Methyl-2-(pyridin-4-yl)thiazole-5-carboxylic acid(cas: 144060-98-0Electric Literature of C10H8N2O2S)
4-Methyl-2-(pyridin-4-yl)thiazole-5-carboxylic acid(cas: 144060-98-0) belongs to pyridine. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. As ligands, solvents, and catalysts they facilitate reactions; thus descriptions of these new ligands and their applications abound each year.Electric Literature of C10H8N2O2S
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica