On April 15, 2020, Malecka, Magdalena; Machura, Barbara; Switlicka, Anna; Kotowicz, Sonia; Szafraniec-Gorol, Grazyna; Siwy, Mariola; Szalkowski, Marcin; Mackowski, Sebastian; Schab-Balcerzak, Ewa published an article.Recommanded Product: 2-Acetylthiazole The title of the article was Towards better understanding of photophysical properties of rhenium(I) tricarbonyl complexes with terpy-like ligands. And the article contained the following:
Series of Re(I) carbonyls complexes were designed and synthesized to explore the impact of the triimine skeleton and number of methoxy groups attached to aryl substituents on their optoelectronic and thermal properties. The chem. structures of the prepared complexes were confirmed by 1H and 13C NMR spectroscopy, HR-MS, elemental anal., and x-ray measurements. DSC measurements showed that they melted in the range of 198-325°. Some of them form stable mol. glasses with high glass transition temperatures (158-173°). Exptl. obtained optical properties were supported by DFT calculations The UV-Vis spectra display a series of overlapping absorption bands in the range 200-350 nm, and much weaker broad band in the visible spectral region, due to intraligand and charge transfer transitions, resp. All synthesized complexes were emissive in solution and in solid state as powder. Moreover, when applied in diodes, some of them exhibited ability for emission of light under external voltage with maximum of electroluminescence band located at 591-630 nm. The experimental process involved the reaction of 2-Acetylthiazole(cas: 24295-03-2).Recommanded Product: 2-Acetylthiazole
The Article related to crystal structure mol rhenium tricarbonyl terpyridine complex optimized dft, rhenium tricarbonyl terpyridine complex preparation photophys thermal optical electrochem, electroluminescence, photoluminescence, re(i) carbonyl, terpy-like ligands and other aspects.Recommanded Product: 2-Acetylthiazole
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica