Filatre-Furcate, Agathe published the artcileGold dithiolene complexes: easy access to 2-alkylthio-thiazoledithiolate complexes, Quality Control of 5053-24-7, the publication is Dalton Transactions (2015), 44(35), 15683-15689, database is CAplus and MEDLINE.
In the presence of MeI or EtI, N-tert-butyl-1,3-thiazoline-2-thione derivatives undergo a transformation to 2-alkylthio-thiazoledithiolate pro-ligands with elimination of the tert-Bu substituent. The corresponding AuIII dithiolene complexes [Au(RS-tzdt)2]– (R = Me, Et) oxidize readily to the neutral radical species, such as the semi-conducting [Au(EtS-tzdt)2]•, which organizes into dimers in the solid state.
Dalton Transactions published new progress about 5053-24-7. 5053-24-7 belongs to thiazole, auxiliary class Thiazole,sulfides, name is 2-(Methylthio)thiazole, and the molecular formula is C4H5NS2, Quality Control of 5053-24-7.
Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica