Ward, E. R.’s team published research in Journal of the Chemical Society in | CAS: 1753-29-3

Journal of the Chemical Society published new progress about 1753-29-3. 1753-29-3 belongs to thiazole, auxiliary class Other Aromatic Heterocyclic,Amine, name is Benzo[d][1,2,3]thiadiazol-5-amine, and the molecular formula is C11H14O4, Application of Benzo[d][1,2,3]thiadiazol-5-amine.

Ward, E. R. published the artcile1,2,3-Benzothiadiazole. III. Electrophilic substitution in 5- and 7-amino-1,2,3-benzothiadiazoles and the preparation of some substituted 1,2,3-benzothiadiazoles, Application of Benzo[d][1,2,3]thiadiazol-5-amine, the publication is Journal of the Chemical Society (1965), 1023-8, database is CAplus.

cf. CA 59:12787f. Bromination, iodination, nitration, and diazo-coupling of 5- and 7-amino-1,2,3-benzothiadiazoles, and some N-acyl derivatives, have been studied. The results largely confirm the interpretation of electrophilic substitution in the 1,2,3-benzothiadiazole system previously advanced. Some bromination reactions probably proceed by mechanisms other than simple electrophilic substitution. Spectroscopic anal. of the mixture of 5- and 7-nitro-1,2,3-benzothiadiazoles, obtained by nitration of the parent compound, shows that the 7-nitro isomer predominates. Preparation of nitro-, amino-, and hydroxy-1,2,3-benzothiadiazoles has been further investigated, particular attention being given to methods involving ring opening of appropriate benzothiazoles. The synthesis of 4-hydroxy-1,2,3-benzothiadiazole, an analog of 8-hydroxyquinoline, is described.

Journal of the Chemical Society published new progress about 1753-29-3. 1753-29-3 belongs to thiazole, auxiliary class Other Aromatic Heterocyclic,Amine, name is Benzo[d][1,2,3]thiadiazol-5-amine, and the molecular formula is C11H14O4, Application of Benzo[d][1,2,3]thiadiazol-5-amine.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica