Chemical-Resistant Green Luminescent Concentrator-Based Photo-Microreactor via One-Touch Assembly of 3D-Printed Modules was written by Ahn, Gwang-Noh;Kim, Mi-Jeong;Yim, Se-Jun;Sharma, Brijesh M.;Kim, Dong-Pyo. And the article was included in ACS Sustainable Chemistry & Engineering in 2022.Synthetic Route of C20H18N2O2S The following contents are mentioned in the article:
The direct use of the most sustainable energy, the sun, for chem. reactions is extremely attractive. This study proposes a green luminescent concentrator-based photo-microreactor (GLC-PM) assembled by flow modules that can be diversely 3D-printed using a photocurable fluoropolymer formulated with a fluorescent dye (Coumarin 6) for enhancing photochem. reactions. The inherently solvent-resistant GLC-flow modules maintain the chem. efficiency without leaching of fluorescent dyes and deposition of photocatalyst on the walls. In particular, the hexagonal GLC modules enable facile assembly into the customized PMs based on the synthesis requirements using built-in magnets for one-touch self-alignment. Moreover, the serially assembled GLC-PM was shown to enhance the photocatalytic reaction of C-C bond formation in the presence of Rose Bengal, and eventually, the GLC-PM formed by clustering serial and radial connections resulted in enhanced conversion and throughput of C-P bond formation in the presence of Eosin-Y. Therefore, the clustered GLC-PM can be considered as a viable and unique scaling strategy for the production of organic compounds, such as a photo-driven mini-plant. This study involved multiple reactions and reactants, such as 3-(Benzo[d]thiazol-2-yl)-7-(diethylamino)-2H-chromen-2-one (cas: 38215-36-0Synthetic Route of C20H18N2O2S).
3-(Benzo[d]thiazol-2-yl)-7-(diethylamino)-2H-chromen-2-one (cas: 38215-36-0) belongs to thiazole derivatives. Thiazoles frequently appear in peptide studies. Thiazoles can also be used as protected formyl groups, which can be released in later stages of complex natural product synthesis.Various laboratory methods exist for the organic synthesis of thiazoles. For example, 2,4-dimethylthiazole is synthesized from thioacetamide and chloroacetone.Synthetic Route of C20H18N2O2S
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica