The 2D MOF nanosheets as an artificial light-harvesting system with enhanced photoelectric switching performance was written by Liu, Lin;Lu, Xue-Ying;Zhang, Mei-Li;Ren, Yi-Xia;Wang, Ji-Jiang;Yang, Xiao-Gang. And the article was included in Inorganic Chemistry Frontiers in 2022.COA of Formula: C20H18N2O2S The following contents are mentioned in the article:
Herein, we report the synthesis, structure and photophys. properties of a novel well-defined layered metal-organic framework (MOF) [Cd(ppda)(mbib)] by the selection of two flexible ligands 1,4-phenylenediacetic acid (ppda) and 1,3-bis(imidazol-1-ylmethyl)benzene (mbib). A facile “top-down” sonication exfoliation method was used to break the interlayer interactions within the MOF, giving rise to 2D MOF nanosheets with ultrathin thickness and large surface areas. The integration of nanosheet donors and coumarin 6 (CM6) acceptors afforded an efficient artificial light-harvesting system, which can largely extend the absorption band from the violet to visible region. Photoelec. measurements reveal highly enhanced photoelec. switching performance with an “on-off” photocurrent ratio of up to 1000, about 33 times higher than that of pristine 2D MOF nanosheets. This study involved multiple reactions and reactants, such as 3-(Benzo[d]thiazol-2-yl)-7-(diethylamino)-2H-chromen-2-one (cas: 38215-36-0COA of Formula: C20H18N2O2S).
3-(Benzo[d]thiazol-2-yl)-7-(diethylamino)-2H-chromen-2-one (cas: 38215-36-0) belongs to thiazole derivatives. The thiazole ring has been identified as a central feature of numerous natural products, perhaps the most famous example of which is epothilone. Electrophilic attack at nitrogen depends on the presence of electron density at nitrogen as well as the position and nature of substituent linked to the thiazole ring.COA of Formula: C20H18N2O2S
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica