Artem’ev, Alexander V.’s team published research in Polyhedron in 151 | CAS: 5053-24-7

Polyhedron published new progress about 5053-24-7. 5053-24-7 belongs to thiazole, auxiliary class Thiazole,sulfides, name is 2-(Methylthio)thiazole, and the molecular formula is C4H5NS2, COA of Formula: C4H5NS2.

Artem’ev, Alexander V. published the artcileCuI-based coordination polymers with 2-thiazolyl sulfide ligands: First examples, COA of Formula: C4H5NS2, the publication is Polyhedron (2018), 171-176, database is CAplus.

The reaction of CuI with 2-(methylthio)thiazole (MTT) in a 1:1 or 2:1 molar ratio (MeCN, rt, 1h) leads to the coordination polymer [CuI(MTT)]n (CP1) or [(CuI)2(MTT)]n (CP2), resp. CP1 consists of (-Cu-I-Cu-I-)n zigzag chains wherein the adjacent Cu atoms are bridged by the MTT ligand through the thiazole N and sulfide S atoms. 1-D chains of CP2 are assembled from corner-sharing [CuI3N] and [CuI3S] tetrahedra, which alternate in a zigzag fashion. By contrast, 2-(methylthio)benzothiazole (MTBT) reacts with CuI, regardless of the reactants ratio, to give the dinuclear complex [Cu2I2(MTBT)2], where the planar [Cu(μ2-I)]2 core is supported by the two ligands in the N-monodentate manner. At ambient temperature, CP1 exhibits a weak yellow luminescence (λmax=570nm), while CP2 emits in the deep-red region (λmax=705nm).

Polyhedron published new progress about 5053-24-7. 5053-24-7 belongs to thiazole, auxiliary class Thiazole,sulfides, name is 2-(Methylthio)thiazole, and the molecular formula is C4H5NS2, COA of Formula: C4H5NS2.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica