Mayr, Sebastian A. published the artcileOxidation of Various Kraft Lignins with a Bacterial Laccase Enzyme, Application In Synthesis of 30931-67-0, the publication is International Journal of Molecular Sciences (2021), 22(23), 13161, database is CAplus and MEDLINE.
Modification of kraft lignin (KL), traditionally uses harsh and energy-demanding phys. and chem. processes. In this study, the potential of the bacterial laccase CotA (spore coating protein A) for oxidation of KL under mild conditions was assessed. Thereby, the efficiency of CotA to oxidize both softwood and hardwood KL of varying purity at alk. conditions was examined For the resp. type of wood, the highest oxidation activity by CotA was determined for the medium ash content softwood KL (MA_S) and the medium ash content hardwood KL (MA_H), resp. By an up to 95% decrease in fluorescence and up to 65% in phenol content coupling of the structural lignin units was indicated. These results correlated with an increase in viscosity and mol. weight, which increased nearly 2 and 20-fold for MA_H and about 1.3 and 6.0-fold for MA_S, resp. Thus, this study confirms that the CotA laccase can oxidize a variety of KL at alk. conditions, while the origin and purity of KL were found to have a major impact on the efficiency of oxidation Under the herein tested conditions, it was observed that the MA_H KL showed the highest susceptibility to CotA oxidation when compared to the other hardwood KLs and the softwood KLs. Therefore, this could be a viable method to produce sustainable resins and adhesives.
International Journal of Molecular Sciences published new progress about 30931-67-0. 30931-67-0 belongs to thiazole, auxiliary class Salt,Hydrazine,Amine,Benzothiazole, name is Ammonium 2,2′-(hydrazine-1,2-diylidene)bis(3-ethyl-2,3-dihydrobenzo[d]thiazole-6-sulfonate), and the molecular formula is C18H24N6O6S4, Application In Synthesis of 30931-67-0.
Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica