Facile synthesis of the new tripodal tetraamine ligand tris(thiazolylmethyl) amine, and full characterization of two ferrous complexes was written by Thibon, Aurore;Karmazin-Brelot, Lydia;Mandon, Dominique. And the article was included in Dalton Transactions in 2013.Quality Control of Thiazol-2-ylmethanamine This article mentions the following:
The authors report the facile synthesis of the new tris(thiazolylmethyl)amine, TTA ligand (3) and the full characterization in solution and in the solid state of two ferrous complexes, [(TTA)FeCl2] (1) and [(TTA)Fe(OTf)2] (2). TTA, the first example of a simple tris(thiazolemethyl)amine chelate – the second one only within this class of tripods – exerts a weak ligand field and the tertiary amine is weakly bound to the metal center. In the experiment, the researchers used many compounds, for example, Thiazol-2-ylmethanamine (cas: 55661-33-1Quality Control of Thiazol-2-ylmethanamine).
Thiazol-2-ylmethanamine (cas: 55661-33-1) belongs to thiazole derivatives. Thiazoles in peptides or their ability to bind proteins, DNA and RNA has led to many synthetic studies and new applications. Electrophilic attack at nitrogen depends on the presence of electron density at nitrogen as well as the position and nature of substituent linked to the thiazole ring.Quality Control of Thiazol-2-ylmethanamine
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica