Cobalt-catalyzed domino C-N cross-coupling reaction between phenyl(2-halo)isothiourea and aryl halide was written by Kondraganti, Lakshmi;Tamminana, Ramana;Nathani, Srinivasa Rao;Babu, Manabolu Surendra;Ramachandran, Dittakavi. And the article was included in Phosphorus, Sulfur and Silicon and the Related Elements in 2021.Application In Synthesis of N-Phenylbenzo[d]thiazol-2-amine This article mentions the following:
A simple route for the synthesis of 2-aminophenyl benzothiazole through domino intra and inter mol. C-N cross-coupling reaction using a cobalt catalyst under mild reaction conditions has been accomplished. The procedure is exptl. simple, general, and efficient. The reaction was readily carried out under optimized reaction conditions to provide target products in moderate to good yield. In the experiment, the researchers used many compounds, for example, N-Phenylbenzo[d]thiazol-2-amine (cas: 1843-21-6Application In Synthesis of N-Phenylbenzo[d]thiazol-2-amine).
N-Phenylbenzo[d]thiazol-2-amine (cas: 1843-21-6) belongs to thiazole derivatives. The thiazole ring is notable as a component of the vitamin thiamine (B1). Various laboratory methods exist for the organic synthesis of thiazoles. Prominent is the Hantzsch thiazole synthesis is a reaction between haloketones and thioamides.Application In Synthesis of N-Phenylbenzo[d]thiazol-2-amine
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica