Ruthenium-catalyzed hydrosilylation of C:N bond in benzothiazole was written by Kucinski, Krzysztof;Hreczycho, Grzegorz. And the article was included in Journal of Organometallic Chemistry in 2017.SDS of cas: 2942-06-5 This article mentions the following:
Various tertiary hydrosilanes are shown to be compatible with ruthenium-catalyzed hydrosilylation of carbon-nitrogen double bond in benzothiazole. The addition reaction was successfully performed by using a catalytic amount of Ru3(CO)12. The products were isolated and characterized by IR, 1H NMR, 13C NMR, 29Si NMR, HRMS and MS anal. This is the first example for the catalytic hydrosilylation of benzothiazole. In the experiment, the researchers used many compounds, for example, 6-Nitrobenzothiazole (cas: 2942-06-5SDS of cas: 2942-06-5).
6-Nitrobenzothiazole (cas: 2942-06-5) belongs to thiazole derivatives. Thiazoles in peptides or their ability to bind proteins, DNA and RNA has led to many synthetic studies and new applications. Various laboratory methods exist for the organic synthesis of thiazoles. Prominent is the Hantzsch thiazole synthesis is a reaction between haloketones and thioamides.SDS of cas: 2942-06-5
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica