Thiazolium as Single-Group Bifunctional Catalyst for Selectively Bulk Melt ROP of Cyclic Esters was written by Tian, Guo-Qiang;Liu, Wen;Chen, Li;Wu, Gang;Chen, Si-Chong;Wang, Yu-Zhong. And the article was included in ChemCatChem in 2019.Recommanded Product: 4209-18-1 This article mentions the following:
Novel single-group bifunctional hydrogen-bonding catalysts based on thiazolium were developed. The integration of hydrogen-bonding donor and acceptor in a single thiazolium ring not only amplified synergetic effect, but also enhanced the stability and the controllability for catalysis, and hence prompt thiazolium an efficient metal-free catalyst for melt ROP of cyclic esters. More interestingly, thiazolium may form a compacted active center with monomer and initiator (or propagating chain end), thus enabling it to selectively activate lower sterically encumbered substrates in ROP. In the experiment, the researchers used many compounds, for example, 3-Benzyl-4-methylthiazol-3-ium chloride (cas: 4209-18-1Recommanded Product: 4209-18-1).
3-Benzyl-4-methylthiazol-3-ium chloride (cas: 4209-18-1) belongs to thiazole derivatives. The thiazole ring has been identified as a central feature of numerous natural products, perhaps the most famous example of which is epothilone. Thiazole is a versatile building block for the construction and lead generation of new drug discoveries. Numerous diazole-based compounds are in clinical use as anticancer, antileukemic, antiinflammatory, antiviral, antifungal, antirheumatic, immunomodulator, and antiparasitic agents.Recommanded Product: 4209-18-1
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica