Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 38894-11-0, Name is 2-Hydrazono-3-methyl-2,3-dihydrobenzo[d]thiazole hydrochloride hydrate, molecular formula is C8H12ClN3OS, belongs to thiazoles compound, is a common compound. In a patnet, author is Ujwaldev, Sankuviruthiyil M., once mentioned the new application about 38894-11-0, Product Details of 38894-11-0.
Novel synthesis of2-Aminothiazolesvia Fe(III)-Iodine-catalyzed Hantzsch-type condensation
A novel iron-iodine catalyzed one pot synthesis of 2-aminothiazoles from methyl aryl ketones and thiourea is demonstrated. This protocol can be considered as a catalyzed version of the classical Hantzsch aminothiazole synthesis as it enables the in situ generation of alpha-iodoketones in the reaction medium using catalytic amount of iodine leading to Hantzsch condensation with thiourea. The supply of iodine for multiple catalytic cycles is ensured by using catalytic amounts of iron as it enables iodide to iodine oxidation. The generality of this protocol is also well established in this manuscript by synthesizing a variety of 2-aminothiazoles from different ketones and thiourea.
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Reference:
Thiazole | C3H3NS – PubChem,
,Thiazole | chemical compound | Britannica