Synthetic Route of 10200-59-6. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 10200-59-6, Name is 2-Thiazolecarboxaldehyde. In a document type is Article, introducing its new discovery.
A series of 2,2?:6?,2?-terpyridine (TPY) based aromatic heterocyclic compounds, extended by thiophene, 4-dibenzothiophene, and thiazole units at the para position of the central pyridine ring in TPY, are described in this paper. A new compound, 4?-(4?-dibenbenzothiophene-5-thiophene-2-yl)-2,2?:6?,2?-terpyridine (La), serves as a tridentate ligand to react with Cu(NO3)2¡¤3H2O and CuCl2¡¤2H2O, respectively, to produce two different Cu(II) complexes [Cu(La)2](NO3)2 and [CuLaCl2] with 1 : 2 and 1 : 1 metal/ligand ratios. Dibenzothiophene is first introduced to TPY via the thiophene bridge. The alterations in cis and trans configuration, dihedral angles between adjacent aromatic rings, and photophysical properties have been observed before and after Cu(II) complexation, which has been verified by their crystal structures, UV?vis and fluorescence spectra.
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Reference£º
Thiazole | C3H4448NS – PubChem,
Thiazole | chemical compound | Britannica