Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 16112-21-3, Name is 2-(4-Methylphenyl)benzothiazole, HPLC of Formula: C14H11NS.
An N-heterocyclic carbene palladium-based complex, cis-dibromo{1,1?- di[3,4,5-trimethoxybenzyl]-3,3?-butylenedibenzimidazol-2, 2?-diylidene}palladium(II), has been synthesized and characterized by elemental analysis, IR spectroscopy and 1H- and 13C-NMR spectroscopy. The crystal and molecular structure of the title compound was determined by single-crystal X-ray diffraction. The title compound consists of a 1,1?-di[3,4,5-trimethoxybenzyl]-3,3?-butylenedibenzimidazole and two bromo ligands coordinated to a palladium atom in a distorted square-planar cis-system. Two benzoimidazole rings are connected to each other by a C 4H8 bridge. The substituted benzimidazole ligand forms a bidentate chelate with palladium, bonding via the carbene carbon atoms. There are two independent molecules A and B in the asymmetric unit. The Pd – Br bonds are 2.4675(14) and 2.4601(13) A, and the Pd – Ccarbene bonds are 1.985(9) and 1.986(9) A for molecule A. Each A and B molecule is stabilized with intra- and inter-molecular hydrogen bonds and C – H…pi interactions. The palladium-carbene complex was tested as a catalyst in the direct arylation of benzothiazole with arylbromides. The most suitable reaction conditions for the direct arylation of benzothiazole with arylbromides are NMP, K3PO4, Pd-NHC and 130 C.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.HPLC of Formula: C14H11NS. In my other articles, you can also check out more blogs about 16112-21-3
Reference：
Thiazole | C3H760NS – PubChem,
Thiazole | chemical compound | Britannica