Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 18362-64-6, is researched, Molecular C9H16O2, about Regioselective Rhodium-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Terminal Alkynes, the main research direction is regioselective rhodium catalyst addition dicarbonyl compound alkyne.Application of 18362-64-6.
A new method for the rhodium-catalyzed regioselective C-C bond formation using terminal alkynes and 1,3-dicarbonyl compounds to achieve valuable branched α-allylated 1,3-dicarbonyl products is reported. With a Rh(I)/DPEphos/p-CF3-benzoic acid as the catalyst system, the desired products can be obtained in good to excellent yields and with perfect regioselectivity. A broad range of functional groups were tolerated, and first exptl. insights of a plausible reaction mechanism were obtained.
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Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica