Gou, Xue-Ya; Zhang, Bo-Sheng; Wang, Xin-Gang; Shi, Wei-Yu; Liu, Hong-Chao; An, Yang; Zhang, Zhe; Liang, Yong-Min published the artcile< Visible-light-induced ligand-free RuCl3 catalyzed C-H phosphorylation in water>, Name: Ethyl 4-methylthiazole-5-carboxylate, the main research area is light ruthenium photocatalyst phosphorylation water green chem arene heteroarene; crystal structure mol phosphine oxide preparation green chem organophosphorus.
Visible-light-induced C-H phosphorylation of para-CAr-H and heteroarenes was realized using cost-effective RuCl3 as a catalyst. The reaction conditions are green and environmentally friendly, using water as a solvent at room temperature and without ligands. A broad range of highly functional organophosphorus compounds were obtained via a cross-dehydrogenation-coupling (CDC) reaction. In addition, we also proved that RuCl3 is a photocatalyst via its absorption spectrum and on/off light experiments
Chemical Communications (Cambridge, United Kingdom) published new progress about Crystal structure. 20582-55-2 belongs to class thiazole, and the molecular formula is C7H9NO2S, Name: Ethyl 4-methylthiazole-5-carboxylate.
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica