Lu, Cui-Fen; Zhang, Shou-Bo; Li, Yan; Yang, Gui-Chun; Chen, Zu-Xing published the artcile< Stereoselective synthesis of (R)-10-methyltridecan-2-one, the sex pheromone of the southern corn rootworm, using (4S)-benzylthiazolidinethione as a chiral auxiliary>, Application In Synthesis of 171877-39-7, the main research area is methyltridecanone stereoselective synthesis Michael addition benzylthiazolidinethione chiral auxiliary.
The stereoselective synthesis of (R)-10-methyltridecan-2-one, the sex pheromone of the southern corn rootworm, was carried out in 20.7% overall yield based on (4S)-benzylthiazolidine-2-thione (five steps). In the crucial step, the stereogenic center was generated by an asym. Michael addition using enantiomerically pure (4S)-benzylthiazolidine-2-thione as a chiral auxiliary.
Tetrahedron: Asymmetry published new progress about Michael reaction, stereoselective. 171877-39-7 belongs to class thiazole, and the molecular formula is C10H11NS2, Application In Synthesis of 171877-39-7.
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica