Hosseini-Sarvari, Mona; Hosseinpour, Zeinab; Koohgard, Mehdi published the artcile< Visible light thiocyanation of N-bearing aromatic and heteroaromatic compounds using Ag/TiO2 nanotube photocatalyst>, Safety of 2-Amino-4-(3-nitrophenyl)thiazole, the main research area is aryl thiocyanate preparation green chem visible light irradiation; pyrrole aniline aminothiazole thiocyanation photocatalyst.
In this study, Ag/TiO2 nanotubes (Ag/TNT) were synthesized via simple hydrothermal process, and this photocatalyst was successfully exploited in thiocyanation reactions at room temperature under visible light irradiation Four classes of important heterocyclic compounds including indole, aniline, pyrrole and 2-aminothiazole derivatives via Ag/TNT treated with ammonium thiocyanate formed the corresponding thiocyano compounds in moderate to excellent yields. Plasmonic property and catalytic performance of Ag nanoparticles (which mainly deposited on the surface of TNT) in absorbing species containing sulfur atoms were key components for the reactions to proceed. This potent, simple and versatile protocol reported for the first time afforded thiocyanation reactions of aniline, pyrrole and 2-aminothiazole derivatives under visible light. The reactions proceeded through a radical pathway by applying air mol. oxygen as a low-cost and environmentally friendly terminal oxidant.
New Journal of Chemistry published new progress about Anilines Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 57493-24-0 belongs to class thiazole, and the molecular formula is C9H7N3O2S, Safety of 2-Amino-4-(3-nitrophenyl)thiazole.
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica