In 2021,New Journal of Chemistry included an article by Borthakur, Priyakshree; Boruah, Purna K.; Das, Punamshree; Das, Manash R.. Computed Properties of C18H24N6O6S4. The article was titled 《CuS nanoparticles decorated MoS2 sheets as an efficient nanozyme for selective detection and photocatalytic degradation of hydroquinone in water》. The information in the text is summarized as follows:
The development of cost effective and efficient nanomaterials with enzyme mimetics and photocatalytic activity has achieved tremendous research interest in the quant. detection as well as removal of toxic environmental pollutants. CuS nanoparticles decorated MoS2 sheets were successfully synthesized adopting a simple hydrothermal technique and using low-cost materials. The nanocomposite was successfully used as an efficient catalyst for the selective detection and removal of a toxic phenolic compound like hydroquinone (HQ). The CuS-MoS2 nanocomposite catalyzed the oxidation of different chromogenic substrates like 3,3′,5,5′-tetramethylbenzidine, 2,2′-azino-bis(3-ethylbenzo-thiazoline-6-sulfonic acid)diammonium salt, and o-phenylenediamine in the presence of H2O2, indicating its peroxidase-like activity as natural Horseradish peroxidase (HRP). The catalytic performance of the nanozyme was further investigated through the typical Michaelis-Menten kinetics. The results showed that the proposed sensor exhibited improved catalytic properties with a wide linear relationship (0.4-50μM) and a low detection limit of 3.68μM for HQ detection in aqueous medium. Meanwhile, the mechanism of HQ sensing in the presence of CuS-MoS2 nanozyme was systematically investigated. Moreover, the CuS-MoS2 nanozyme possessed significant photocatalytic activity and 83% HQ decomposition was achieved within 240 min under irradiation of natural sunlight. The mechanism of enhanced photocatalytic degradation of HQ through the formation of OH radicals as reactive species was evidenced by analyzing the formation of fluorescent active mols. on the addition of terephthalic acid and by high-resolution mass spectrometry. Thus CuS-MoS2 represents a new and promising HQ sensing material in a highly sensitive and fast manner as well as an efficient photocatalyst for the degradation of HQ to its non-toxic products under natural sunlight irradiation The experimental part of the paper was very detailed, including the reaction process of ABTS Diammonium(cas: 30931-67-0Computed Properties of C18H24N6O6S4)
ABTS Diammonium(cas: 30931-67-0) belongs to anime. Amines characteristically form salts with acids; a hydrogen ion, H+, adds to the nitrogen. With the strong mineral acids (e.g., H2SO4, HNO3, and HCl), the reaction is vigorous. Salt formation is instantly reversed by strong bases such as NaOH. Neutral electrophiles (compounds attracted to regions of negative charge) also react with amines; alkyl halides (R′X) and analogous alkylating agents are important examples of electrophilic reagents.Computed Properties of C18H24N6O6S4
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica