Bastianelli, Pierre published the artcileSynthesis in the 2-alkylthiothiazole series, Recommanded Product: 2-(Methylthio)thiazole, the publication is Bulletin de la Societe Chimique de France (1967), 1948-51, database is CAplus.
4-Thiazoline-2-thione (I) is prepared II are prepared from I, and N.M.R. data for the II are obtained. Thus, NH3 is introduced into a solution of CS2 in iso-PrOAc to give H2NCS2NH4; a solution of 143 g. H2NCS2NH4 in 250 ml. water is treated with 87.5 g. ClCH2CHO in water or EtOH to give 55% I, m. 80° (water). A mixture of 10 g. I, 25 g. MeI, and 200 ml. MeNO2 is refluxed 30 min. to give 90% 2-methylthiothiazole, b2 68°. Similarly prepared are the following II (R, b.p./mm., and % yield given): Et, 70°/2, 90; Pr, 54°/1, 80; iso-Pr, 66°/5, 80; tert-Bu, -, 53; PhCH2, 162°/2, 68. N.M.R., ir, and Rf (thin-layer chromatog.) data for the prepared II are given. According to the N.M.R. data, the protons of the side chains are deshielded by the thiazole ring.
Bulletin de la Societe Chimique de France published new progress about 5053-24-7. 5053-24-7 belongs to thiazole, auxiliary class Thiazole,sulfides, name is 2-(Methylthio)thiazole, and the molecular formula is C4H5NS2, Recommanded Product: 2-(Methylthio)thiazole.
Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica