Category: 2942-13-4

Reference of 2942-13-4. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 2942-13-4, Name is 6-Methoxybenzo[d]thiazole. In a document type is Article, introducing its new discovery.

The direct phosphorylation of (benzo)thiazoles with various H-phosphine oxides was realized by using K2S2O8 as the oxidant. A series of 2-phosphoryl (benzo)thiazoles were obtained in moderate to good yields.

The direct phosphorylation of (benzo)thiazoles with various H-phosphine oxides was realized by using K2S2O8 as the oxidant. A series of 2-phosphoryl (benzo)thiazoles were obtained in moderate to good yields.

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Reference£º
Thiazole | C3H7162NS – PubChem,
Thiazole | chemical compound | Britannica

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 2942-13-4, Name is 6-Methoxybenzo[d]thiazole, molecular formula is C8H7NOS. In a Article£¬once mentioned of 2942-13-4, Formula: C8H7NOS

The one-pot reactions of imidazoles with allyltributyltin in the presence of alkyl chloroformates gave 2-allyl-1,3-bis(alkoxycarbonyl)-4-imidazolines in good yields.The reactions of thiazoles and oxazoles also proceeded in a similar manner.The instability of the intermediary quaternary salts required the nucleophiles to be added simultaneously with the chloroformate.Therefore, the reaction was specific for allyltributyltin, since it doesn’t react with the carbonyl group of chloroformates.The dihydro allyl adducts thus obtained were aromatized with potassium ferricyanide under basic conditions to afford the corresponding 2-allylazoles.

The one-pot reactions of imidazoles with allyltributyltin in the presence of alkyl chloroformates gave 2-allyl-1,3-bis(alkoxycarbonyl)-4-imidazolines in good yields.The reactions of thiazoles and oxazoles also proceeded in a similar manner.The instability of the intermediary quaternary salts required the nucleophiles to be added simultaneously with the chloroformate.Therefore, the reaction was specific for allyltributyltin, since it doesn’t react with the carbonyl group of chloroformates.The dihydro allyl adducts thus obtained were aromatized with potassium ferricyanide under basic conditions to afford the corresponding 2-allylazoles.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C8H7NOS. In my other articles, you can also check out more blogs about 2942-13-4

Reference£º
Thiazole | C3H7144NS – PubChem,
Thiazole | chemical compound | Britannica

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.2942-13-4, Name is 6-Methoxybenzo[d]thiazole, molecular formula is C8H7NOS. In a Article£¬once mentioned of 2942-13-4, Recommanded Product: 6-Methoxybenzo[d]thiazole

Nickel can be used to promote oxidative C(sp2)?H/C(sp2)?H cross-coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional-group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.

Nickel can be used to promote oxidative C(sp2)?H/C(sp2)?H cross-coupling between two heteroarenes. The reaction scope can be extended to aromatic carboxamides as the coupling partner. The reaction exhibits high functional-group compatibility and broad substrate scope. The silver oxidant can be recycled to reduce costs and waste, which is very useful for practical applications.

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 2942-13-4 is helpful to your research., Recommanded Product: 6-Methoxybenzo[d]thiazole

Reference£º
Thiazole | C3H7174NS – PubChem,
Thiazole | chemical compound | Britannica

Application of 2942-13-4. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 2942-13-4, Name is 6-Methoxybenzo[d]thiazole. In a document type is Article, introducing its new discovery.

A cobalt-catalyzed decarboxylative cross-coupling reaction of (hetero)aryl carboxylic acids with benzothiazoles or benzoxazoles is reported. This represents a first example of metal-catalyzed decarboxylative C-H heteroarylation of benzo-fused heterocycles. The transformation provides a convenient route, with good yields and functional group tolerance, to various important arylheteroaryl and unsymmetrical biheteroaryl structural motifs.

A cobalt-catalyzed decarboxylative cross-coupling reaction of (hetero)aryl carboxylic acids with benzothiazoles or benzoxazoles is reported. This represents a first example of metal-catalyzed decarboxylative C-H heteroarylation of benzo-fused heterocycles. The transformation provides a convenient route, with good yields and functional group tolerance, to various important arylheteroaryl and unsymmetrical biheteroaryl structural motifs.

If you are interested in 2942-13-4, you can contact me at any time and look forward to more communication.Application of 2942-13-4

Reference£º
Thiazole | C3H7239NS – PubChem,
Thiazole | chemical compound | Britannica

In an article, published in an article, once mentioned the application of 2942-13-4, Name is 6-Methoxybenzo[d]thiazole,molecular formula is C8H7NOS, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of 6-Methoxybenzo[d]thiazole

A metal-organic framework Fe3O(BDC)3 was synthesized and used as a recyclable heterogeneous catalyst for the direct arylation of azoles with benzaldehydes. Following this protocol, inexpensive and commercially available benzaldehydes could act as an aryl source for the transformation, replacing the aryl halides normally employed in the conventional cross-coupling reactions. The catalyst disclosed higher catalytic productivity for the formation of aryl-substituted azoles than various MOFs and diverse homogeneous iron catalysts. The conversion was considerably regulated by the solvent and the oxidant, and the combination of N-methyl-2-pyrrolidone with di-tert-butyl peroxide offered the best yield. Heterogeneous catalysis was verified for the reaction, and the production of aryl-substituted azoles was only feasible in the presence of the iron framework. It was possible to reuse the catalyst for the direct arylation of azoles with aldehydes while its catalytic activity was preserved for multiple cycles. To our best judgment, this direct arylation of azoles with aldehydes utilizing solid catalysts has not been previously reported.

A metal-organic framework Fe3O(BDC)3 was synthesized and used as a recyclable heterogeneous catalyst for the direct arylation of azoles with benzaldehydes. Following this protocol, inexpensive and commercially available benzaldehydes could act as an aryl source for the transformation, replacing the aryl halides normally employed in the conventional cross-coupling reactions. The catalyst disclosed higher catalytic productivity for the formation of aryl-substituted azoles than various MOFs and diverse homogeneous iron catalysts. The conversion was considerably regulated by the solvent and the oxidant, and the combination of N-methyl-2-pyrrolidone with di-tert-butyl peroxide offered the best yield. Heterogeneous catalysis was verified for the reaction, and the production of aryl-substituted azoles was only feasible in the presence of the iron framework. It was possible to reuse the catalyst for the direct arylation of azoles with aldehydes while its catalytic activity was preserved for multiple cycles. To our best judgment, this direct arylation of azoles with aldehydes utilizing solid catalysts has not been previously reported.

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Reference£º
Thiazole | C3H7224NS – PubChem,
Thiazole | chemical compound | Britannica

Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 2942-13-4, C8H7NOS. A document type is Patent, introducing its new discovery., Recommanded Product: 6-Methoxybenzo[d]thiazole

A double-phosphate process for the preparation of derivatives […], accelerator is characterized in that the iodine, in the organic solvent, azole derivatives with phosphorous acid ester by 1:1-3 the molar ratio of the, reaction at normal temperature and pressure 10 minutes; after the reaction solvent is pumped, column chromatography, eluent: V/petroleum ether: ethyl acetate = 5/V:1-1:1, to get double phosphate ester addition of the azole derivatives. The […] derivative as oxazole derivatives, thiazole derivatives or imidazole derivatives. Raw materials and catalyst of the present invention is cheap, simple synthesis process, and for the first time achieves the double phosphorylation reaction; mild reaction conditions, high yield, easy industrialization; reaction raw materials and catalyst cleaning non-toxic, small pollution to the environment. (by machine translation)

A double-phosphate process for the preparation of derivatives […], accelerator is characterized in that the iodine, in the organic solvent, azole derivatives with phosphorous acid ester by 1:1-3 the molar ratio of the, reaction at normal temperature and pressure 10 minutes; after the reaction solvent is pumped, column chromatography, eluent: V/petroleum ether: ethyl acetate = 5/V:1-1:1, to get double phosphate ester addition of the azole derivatives. The […] derivative as oxazole derivatives, thiazole derivatives or imidazole derivatives. Raw materials and catalyst of the present invention is cheap, simple synthesis process, and for the first time achieves the double phosphorylation reaction; mild reaction conditions, high yield, easy industrialization; reaction raw materials and catalyst cleaning non-toxic, small pollution to the environment. (by machine translation)

Interested yet? Keep reading other articles of 2942-13-4!, Recommanded Product: 6-Methoxybenzo[d]thiazole

Reference£º
Thiazole | C3H7229NS – PubChem,
Thiazole | chemical compound | Britannica

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.2942-13-4, Name is 6-Methoxybenzo[d]thiazole, molecular formula is C8H7NOS. In a Patent£¬once mentioned of 2942-13-4, Recommanded Product: 6-Methoxybenzo[d]thiazole

The invention discloses a substituted benzo thiazole C2 alkylation derivative and its application, the structural formula of the compound of formula (I) as shown: Formula (I) in, benzothiazole ring substituent R is H1 Mono-substituted, multi-substituted or not substituted; n is 0 – 4 of the integer, n said benzothiazole ring substituent R1 The number of; n=0 when, said of the benzothiazole ring H is not substituted; n=1 when, said benzothiazole ring substituent R is H1 Mono-substituted; n=2 – 4 when, said benzothiazole ring substituent R is H1 Multi-substituted, different substituted position substituent on R1 The same or different; the substituent R1 Is hydrogen, C1 – C3 alkyl, C1 – C2 alkoxy, aryl or halogen; formula (I) substituent R2 Is hydrogen or C1 – C3 alkyl. The present invention provides substituted benzothiazole C2 alkylation derivatives, exhibit better bacteriostatic activity, in particular against the dry silk nuclear fungus and exhibits a strong inhibiting activity. (by machine translation)

The invention discloses a substituted benzo thiazole C2 alkylation derivative and its application, the structural formula of the compound of formula (I) as shown: Formula (I) in, benzothiazole ring substituent R is H1 Mono-substituted, multi-substituted or not substituted; n is 0 – 4 of the integer, n said benzothiazole ring substituent R1 The number of; n=0 when, said of the benzothiazole ring H is not substituted; n=1 when, said benzothiazole ring substituent R is H1 Mono-substituted; n=2 – 4 when, said benzothiazole ring substituent R is H1 Multi-substituted, different substituted position substituent on R1 The same or different; the substituent R1 Is hydrogen, C1 – C3 alkyl, C1 – C2 alkoxy, aryl or halogen; formula (I) substituent R2 Is hydrogen or C1 – C3 alkyl. The present invention provides substituted benzothiazole C2 alkylation derivatives, exhibit better bacteriostatic activity, in particular against the dry silk nuclear fungus and exhibits a strong inhibiting activity. (by machine translation)

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: 6-Methoxybenzo[d]thiazole, you can also check out more blogs about2942-13-4

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Thiazole | C3H7153NS – PubChem,
Thiazole | chemical compound | Britannica

2942-13-4, Name is 6-Methoxybenzo[d]thiazole, molecular formula is C8H7NOS, belongs to thiazole compound, is a common compound. In a patnet, once mentioned the new application about 2942-13-4, SDS of cas: 2942-13-4

The visible-light-promoted oxidant-free decarboxylative C-H adamantylation of azoles was accomplished under ambient reaction conditions. The novel acridinium photocatalyst and cobalt synergistic catalysis enabled the C-H adamantylation under oxidant-free reaction conditions. This C-H adamantylation strategy proved viable for a wide range of substituted azoles, including benzothiazole, benzoxazole, and benzimidazoles as well as caffeine derivatives, providing an expedient access to 2-adamantyl-substituted azoles.

The visible-light-promoted oxidant-free decarboxylative C-H adamantylation of azoles was accomplished under ambient reaction conditions. The novel acridinium photocatalyst and cobalt synergistic catalysis enabled the C-H adamantylation under oxidant-free reaction conditions. This C-H adamantylation strategy proved viable for a wide range of substituted azoles, including benzothiazole, benzoxazole, and benzimidazoles as well as caffeine derivatives, providing an expedient access to 2-adamantyl-substituted azoles.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.SDS of cas: 2942-13-4. In my other articles, you can also check out more blogs about 2942-13-4

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Thiazole | C3H7136NS – PubChem,
Thiazole | chemical compound | Britannica

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.2942-13-4, Name is 6-Methoxybenzo[d]thiazole, molecular formula is C8H7NOS. In a Article£¬once mentioned of 2942-13-4, name: 6-Methoxybenzo[d]thiazole

The reactions between lithium-benzothiazoles and (S)-N-tert-butanesulfinylketimines have been found to be of general synthetic importance for asymmetric preparation of previously unknown type of amino-benzothiazol derivatives of high pharmaceutical potential. In most cases, the reactions proceed with excellent diastereoselectivities and good isolated yields of the target compounds rendering the developed procedure of high synthetic value and immediate practical use. This journal is

The reactions between lithium-benzothiazoles and (S)-N-tert-butanesulfinylketimines have been found to be of general synthetic importance for asymmetric preparation of previously unknown type of amino-benzothiazol derivatives of high pharmaceutical potential. In most cases, the reactions proceed with excellent diastereoselectivities and good isolated yields of the target compounds rendering the developed procedure of high synthetic value and immediate practical use. This journal is

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 2942-13-4 is helpful to your research., name: 6-Methoxybenzo[d]thiazole

Reference£º
Thiazole | C3H7140NS – PubChem,
Thiazole | chemical compound | Britannica

Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 2942-13-4, Name is 6-Methoxybenzo[d]thiazole, category: thiazole.

A novel way to synthesize 2-arylbenzothiazoles is described. Reactions of benzothiazoles with diverse benzylamines in the presence of K2S 2O8 and KOt-Bu in DMSO-H2O afforded the desired 2-arylbenzothiazoles in good yields. It is notable that no transition-metal catalyst is needed in this reaction. Compared with other known methods, this method of synthesizing 2-arylbenzothiazoles can be advantageous in cases where substituted benzothiazoles and benzylamines are readily available. Georg Thieme Verlag Stuttgart. New York.

A novel way to synthesize 2-arylbenzothiazoles is described. Reactions of benzothiazoles with diverse benzylamines in the presence of K2S 2O8 and KOt-Bu in DMSO-H2O afforded the desired 2-arylbenzothiazoles in good yields. It is notable that no transition-metal catalyst is needed in this reaction. Compared with other known methods, this method of synthesizing 2-arylbenzothiazoles can be advantageous in cases where substituted benzothiazoles and benzylamines are readily available. Georg Thieme Verlag Stuttgart. New York.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: thiazole. In my other articles, you can also check out more blogs about 2942-13-4

Reference£º
Thiazole | C3H7220NS – PubChem,
Thiazole | chemical compound | Britannica