Category: 56503-96-9

Mohinuddin, Pinjari K. Md. published the artcileMontmorillonite K-10 Clay Mediated Green Synthesis of 2-Amino-4-aryl thiazole Derivatives from α-Brominated Aralkyl Ketones in Water, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine, the publication is Current Green Chemistry (2015), 2(2), 163-169, database is CAplus.

Montmorillonite K-10 clay has been identified as an efficient and green catalyst for the synthesis of 2-amino-4-aryl thiazole derivatives I (R = 4-H₃CC₆H₄, 1-naphthyl, 2-naphthyl, etc.; R¹ = H, CH₃) in good to excellent isolated yields (80-96%) from α-brominated aralkyl ketones RC(O)C(R¹)Br and thiourea in aqueous medium at 25-30 °C. The present procedure offers advantages of short reaction time, simple work-up, high yields of products and the catalyst is environmentally benign and exhibits remarkable reusable activity by four times.

Current Green Chemistry published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C13H10N2S, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Rajitha, Kamalon published the artcileSynthesis of graphene oxide-based nanofillers and their influence on the anticorrosion performance of epoxy coating in saline medium, COA of Formula: C13H10N2S, the publication is Diamond and Related Materials (2020), 107974, database is CAplus.

The present study investigated the anticorrosion performance of epoxy coating by the incorporation of two different functionalized graphene oxides as nanofillers in saline media. GO was functionalized with 2-aminothiazole (AT) and 2-amino-4-(1-Naphthyl)Thiazole (ANT) and modified compounds were characterized by X-ray diffraction (XRD), Fourier transform IR spectroscopy (FT-IR), Thermogravimetric anal. (TGA), Raman spectroscopy, and SEM. 0.2 Weight% of neat epoxy and epoxy nanocomposites (GO-AT/EP and GO-ANT/EP) were coated on mild steel substrate by a spin coating method and the formation of a protective film on the steel surface was confirmed using SEM, Atomic Force Microscopy (AFM) and contact angle test. The electrochem. impedance spectroscopy was employed to study the corrosion protection properties of nanocomposite coatings in 3.5% NaCl medium. The results signify the better anticorrosion performance of nanocomposite coatings due to their two-dimensional sheet structures, uniform dispersion and exfoliation in the epoxy matrix, hydrophobic nature and stopping up tiny pores properties. The GO-ANT/EP coating exhibited higher coating resistance (6.598 x 107 Ω cm²) than GO-AT/EP (1.017 x 105 Ω cm²) and pure epoxy (1270 Ω cm²) coating. The crowded structure of GO-ANT helps in forming highly crosslinked compact epoxy coating and therefore displays excellent corrosion protection efficiency than other coatings.

Diamond and Related Materials published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C13H10N2S, COA of Formula: C13H10N2S.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Mohinuddin, Pinjari K. Md. published the artcileMontmorillonite K-10 Clay Mediated Green Synthesis of 2-Amino-4-aryl thiazole Derivatives from α-Brominated Aralkyl Ketones in Water, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine, the publication is Current Green Chemistry (2015), 2(2), 163-169, database is CAplus.

Montmorillonite K-10 clay has been identified as an efficient and green catalyst for the synthesis of 2-amino-4-aryl thiazole derivatives I (R = 4-H₃CC₆H₄, 1-naphthyl, 2-naphthyl, etc.; R¹ = H, CH₃) in good to excellent isolated yields (80-96%) from α-brominated aralkyl ketones RC(O)C(R¹)Br and thiourea in aqueous medium at 25-30 °C. The present procedure offers advantages of short reaction time, simple work-up, high yields of products and the catalyst is environmentally benign and exhibits remarkable reusable activity by four times.

Current Green Chemistry published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C13H10N2S, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Lynch, Daniel E. published the artcileThe hydrogen-bonding networks of 2-amino-4-phenyl-1,3-thiazole derivatives, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine, the publication is Crystal Engineering (2002), 5(2), 123-136, database is CAplus.

The solid-state packing arrays of nine 4-Ph substituted 2-amino-1,3-thiazoles were examined and their H-bonding networks discussed. The nine compounds, in addition to 2-amino-1,3-thiazole 1, were 2-amino-4-phenyl-1,3-thiazole 2, 2-amino-4-phenyl-1,3-thiazolium bromide monohydrate 3, Et 2-amino-4-phenyl-1,3-thiazole-5-carboxylate 4, 2-amino-4-(3-coumarin)-1,3-thiazole 5, 2-amino-4-(4-methylphenyl)-1,3-thiazole 6, 2-amino-4-(2-hydroxyphenyl)-1,3-thiazole 7, 2-amino-4-(4-bisphenyl)-1,3-thiazole 8, 2-amino-4-(1-naphthyl)-1,3-thiazole 9, and 2-amino-4-(2-naphthyl)-1,3-thiazolium bromide 10. The single-crystal x-ray structures of 1-5 were previously reported while the structures of 6-10 are presented. A variety of different packing motifs are observed with only four (4, 5, 6 and 9) exhibiting the characteristic R₂²(8) H-bonded 2-amino-1,3-thiazole dimers. In two of these four structures (6 and 9) potential N-H…π H-bonding interactions exist whereas all remaining structures exhibit a combination of N-H…N with either N-H…O, N-H…S or N-H…Br associations in their H-bonding networks.

Crystal Engineering published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C13H10N2S, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Dash, B. published the artcileFungicidal activities and mass spectral studies of some Schiff bases derived from p-hydroxybenzaldehyde and their derivatives, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine, the publication is Journal of the Indian Chemical Society (1984), 61(11-12), 1061-4, database is CAplus.

A new series of Schiff bases were prepared Condensation of 2-aminothiazoles and -benzothiazoles with p-HOC₆H₄CHO gave I [R = H, R¹ = aryl, R² = H, aryl, R²R² = (un)substituted CH:CHCH:CH]. Chloroacetylation of I (R = H) followed by substitution with morpholine and piperidine gave I (R = morpholinoacetyl, piperidinoacetyl). Cycloaddition of I (R = H) with HSCH₂CO₂H yielded thiazolidinone derivatives II. I and II have satisfactory fungicidal activity against Curvularia at 500 ppm. The mass spectra of I (R = H) were discussed.

Journal of the Indian Chemical Society published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C13H10N2S, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Tripathy, H. published the artcileChlorination of 2-aminothiazoles and the use of chlorinated thiazoles as possible fungicides, Safety of 4-(Naphthalen-1-yl)thiazol-2-amine, the publication is Journal of the Indian Chemical Society (1975), 52(8), 766-7, database is CAplus.

Nine chlorothiazoles (I; R = Ph, substituted phenyl, C10H7, PhCH2CH2, p-MeOC6H4CH2CH2; R1 = Cl) were prepared by chlorination of I·HCl (R as above, R1 = H) with Cl in AcOH, and basifying the products with NH3. I (R1 = Cl) were much more fungicidally active against Piricularia oryzae than I (R1 = H).

Journal of the Indian Chemical Society published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C14H10N2O, Safety of 4-(Naphthalen-1-yl)thiazol-2-amine.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Chen, Yuncan published the artcileSynthesis of 2-aminothiazoles via rhodium-catalyzed carbenoid insertion/annulation of sulfoxonium ylides with thioureas, Name: 4-(Naphthalen-1-yl)thiazol-2-amine, the publication is Chinese Chemical Letters (2021), 32(8), 2555-2558, database is CAplus.

Sulfoxonium ylides as carbene precursors couple smoothly with thioureas in the presence of 5 mol% of rhodium(II) acetate dimmer via carbenoid insertion to afford the corresponding 2-aminothiazoles with high chemoselectivity, provided a facile and efficient approach to access a variety of 2-aminothiazole derivatives with good functional groups tolerance.

Chinese Chemical Letters published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C13H10N2S, Name: 4-(Naphthalen-1-yl)thiazol-2-amine.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Shrivastava, A. K. published the artcile2-Amino-4-arylthiazoles and their thiazolylamides as antifungal agents. 1, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine, the publication is Journal of the Institution of Chemists (India) (1997), 69(4), 113-115, database is CAplus.

Thirty-six title compounds were prepared by standard procedures and their fungicidal activity tested against Fusarium solani. The amides showed greater fungitoxicity than the parent thiazoles in all cases.

Journal of the Institution of Chemists (India) published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C25H47NO8, Recommanded Product: 4-(Naphthalen-1-yl)thiazol-2-amine.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Shrivastava, A. K. published the artcileSyntheses of some 2-amino-4-(aryl/substituted aryl)thiazoles and their thiazolylamides as potential antifungal agents. II, Product Details of C13H10N2S, the publication is Journal of the Institution of Chemists (India) (1997), 69(6), 167-168, database is CAplus.

Thiazolylamides I [R¹ = (un)substituted Ph, 1-naphthyl, 1-hydroxy-2-naphthyl, 4-nitroanilino; R² = 2-HOC₆H₄CO, PhCH₂CO, ClCH₂CO, 3-MeC₆H₄CO, p-xylene-2-sulfonyl] were prepared by reaction of I (same R¹, R² = H) with acid chlorides. The amides were tested for fungicidal and bactericidal activity.

Journal of the Institution of Chemists (India) published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C18H10, Product Details of C13H10N2S.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica

Muthyala, Manoj Kumar published the artcileA novel and efficient one pot synthesis of 2,4-disubstituted thiazoles and oxazoles using phenyltrimethylammonium tribromide in ionic liquid, SDS of cas: 56503-96-9, the publication is Journal of Heterocyclic Chemistry (2012), 49(4), 959-964, database is CAplus.

A novel and efficient 1-pot procedure was described for synthesis of 2,4-disubstituted thiazoles and oxazoles from substituted ketones using phenyltrimethylammonium tribromide as in-situ brominating agent followed by reaction with thioamide/thiourea and amides/ureas, resp. in [bmim][BF₄] ionic liquid The advantages of the procedure include avoiding the handling of lacrymetric compounds and hazardous and toxic organic solvents along with good to excellent yields of the products.

Journal of Heterocyclic Chemistry published new progress about 56503-96-9. 56503-96-9 belongs to thiazole, auxiliary class Thiazole,Amine,Naphthalene, name is 4-(Naphthalen-1-yl)thiazol-2-amine, and the molecular formula is C13H10N2S, SDS of cas: 56503-96-9.

Referemce:
https://pubchem.ncbi.nlm.nih.gov/compound/thiazole,
Thiazole | chemical compound | Britannica