Category: 92-71-7

Name: 2,5-Diphenyloxazole. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 2,5-Diphenyloxazole, is researched, Molecular C15H11NO, CAS is 92-71-7, about Silver-Induced [3+2] Cycloaddition of Isocyanides with Acyl Chlorides: Regioselective Synthesis of 2,5-Disubstituted Oxazoles. Author is Liu, Jian-Quan; Shen, Xuanyu; Shatskiy, Andrey; Zhou, Enlong; Kaerkaes, Markus D.; Wang, Xiang-Shan.

A silver-induced cycloaddition of isocyanides with acyl chlorides were developed. This transition metal-catalyzed strategy provided an effective and scalable approach for the formation of 2,5-disubstituted oxazoles in good to high yields. The employed silver-based MOF catalyst can be efficiently recycled without compromising the yield.

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Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

Name: 2,5-Diphenyloxazole. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 2,5-Diphenyloxazole, is researched, Molecular C15H11NO, CAS is 92-71-7, about Development, characterisation, and deployment of the SNO+ liquid scintillator.

A liquid scintillator consisting of linear alkylbenzene as the solvent and 2,5-diphenyloxazole as the fluor was developed for the SNO+ experiment This mixture was chosen as it is compatible with acrylic and has a competitive light yield to pre-existing liquid scintillators while conferring other advantages including longer attenuation lengths, superior safety characteristics, chem. simplicity, ease of handling, and logistical availability. Its properties have been extensively characterized and are presented here. This liquid scintillator is now used in several neutrino physics experiments in addition to SNO+.

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Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 2,5-Diphenyloxazole(SMILESS: C1(C2=CC=CC=C2)=NC=C(C3=CC=CC=C3)O1,cas:92-71-7) is researched.Name: 2,5-Diphenyloxazole. The article 《Enhancement in photoluminescence properties of organic compound PS/PPO by cerium fluoride nanoparticles doping》 in relation to this compound, is published in SN Applied Sciences. Let’s take a look at the latest research on this compound (cas:92-71-7).

Herein, a new polymeric nanocomposite of 2,5-diphenyloxazole (PPO) and polystyrene (PS) doped with cerium fluoride (CeF3) nanoparticles (PS/PPO/CeF3) was prepared, characterized and its photoluminescence property was reported for the first time. The PS as a base matrix and PPO as a fluor were chose for a scintillator solution substrate and CeF3 nanoparticles dispersed into it to construct a new nanocomposite scintillator. The PS liquid polymeric matrix with 0.5 wt% of PPO was loaded with different percentage of CeF3 nanoparticles. Structural characterizations showed successful preparation of nanocomposites and a mean size of CeF3 nanoparticles as (13 ± 3) nm in the base polymer matrix. The measured photoluminescence showed an enhancement about 3 times in comparison to PS/PPO composite when 10% of CeF3 nanoparticles doped into the polymeric composite matrix under UV excitation. This effect is due to fluorescence resonance energy transfer in Ce3+ ions (5d → 4f transition energy) to the PPO within the PS/PPO/CeF3 nanocomposite. Observed results were presented and discussed.

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Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

Quality Control of 2,5-Diphenyloxazole. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: 2,5-Diphenyloxazole, is researched, Molecular C15H11NO, CAS is 92-71-7, about Bimetallic Cooperative Catalysis for Decarbonylative Heteroarylation of Carboxylic Acids via C-O/C-H Coupling. Author is Liu, Chengwei; Ji, Chong-Lei; Zhou, Tongliang; Hong, Xin; Szostak, Michal.

Cooperative bimetallic catalysis is a fundamental approach in modern synthetic chem. We report bimetallic cooperative catalysis for the direct decarbonylative heteroarylation of ubiquitous carboxylic acids via acyl C-O/C-H coupling [e.g., benzoxazole + benzoic acid → 2-phenylbenzoxazole (92%)]. This novel catalytic system exploits the cooperative action of a copper catalyst and a palladium catalyst in decarbonylation, which enables highly chemoselective synthesis of important heterobiaryl motifs through the coupling of carboxylic acids with heteroarenes in the absence of prefunctionalization or directing groups. This cooperative decarbonylative method uses common carboxylic acids and shows a remarkably broad substrate scope (>70 examples), including late-stage modification of pharmaceuticals and streamlined synthesis of bioactive agents. Extensive mechanistic and computational studies were conducted to gain insight into the mechanism of the reaction. The key step involves intersection of the two catalytic cycles via transmetalation of the copper-aryl species with the palladium(II) intermediate generated by oxidative addition/decarbonylation.

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Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 92-71-7, is researched, Molecular C15H11NO, about Pd/Cu-Catalyzed C-H/C-H cross coupling of (hetero)arenes with azoles through arylsulfonium intermediates, the main research direction is aryl azole preparation chemoselective regioselective; arylsulfonium triflate azole cross coupling palladium copper catalyst; arene azole cross coupling palladium copper catalyst.Name: 2,5-Diphenyloxazole.

A highly efficient method for the selective formal C-H/C-H cross-coupling of 1,3-benzoxazole and (hetero)arenes was established through arylsulfonium intermediates under transition-metal catalysis, which produced a variety of 2-(hetero)aryl azoles RR1 [R = 4-MeC6H4, 4-MeOC6H4, 6-methoxy-3-pyridyl, etc.; R1 = 1,3-benzoxazol-2-yl] in good to excellent yields. Advantages of the reaction included mildness, a good functional group tolerance, a wide range of substrates, a high regio- and chemoselectivity, one-pot procedures and the late-stage functionalization of complex mols. without the use of oxidants, offering a promising strategy for the transition-metal-catalyzed C-H arylation of azoles.

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Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

COA of Formula: C15H11NO. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 2,5-Diphenyloxazole, is researched, Molecular C15H11NO, CAS is 92-71-7, about Palladium/copper-catalyzed decarbonylative heteroarylation of amides via C-N bond activation. Author is Zhou, Ping-Xin; Shi, Shuai; Wang, Jia; Zhang, Yalei; Li, Changzheng; Ge, Chunpo.

A novel strategy for the synthesis of 2-arylated oxazole derivatives, e.g., 5-(1-naphthalenyl)-2-phenyloxazole via palladium/copper-catalyzed decarbonylative heteroarylation of amides RC(O)NR1R2 (R = C6H5, 2-FC6H4, 1-naphthyl, etc.; R1R2 = -C(O)(CH2)3C(O)-, -C(O)(CH2)2C(O)-) via C-N bond activation by ground-state destabilization has been reported. This transformation shows good functional group tolerance and delivers the versatile 2-arylated oxazole derivatives in moderate to good yields. This transformation provides unique and efficient strategies for converting readily available amides and the precursor carboxylic acids into valuable chems.

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Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 2,5-Diphenyloxazole( cas:92-71-7 ) is researched.SDS of cas: 92-71-7.Yang, Yuzi; Ling, Jiajie published the article 《Research on Liquid Scintillator Energy Nonlinearity》 about this compound( cas:92-71-7 ) in Lepton Photon Interations at High Energies, Proceedings of the Internationa Symposium on Lepton Photon Interactions at High Energies, 28th, Guangzhou, China, Aug. 7-12, 2017. Keywords: neutrino energy nonlinearity liquid scintillator. Let’s learn more about this compound (cas:92-71-7).

Liquid scintillator(LS) calorimeter is a classical technol. in the particle physics, especially for the reactor neutrino experiments, which is widely used for detecting electron anti-neutrinos though the inverse beta decay interaction channel. Because of the quenching effect, the scintillator detector has nonlinear energy response. It is critical to accurately measure the scintillator energy response for both the precision measurement of reactor antineutrino energy spectrum in Daya Bay Experiment and the neutrino mass hierarchy measurement determination in JUNO experiments There are several bench measurements of the liquid scintillator energy nonlinearity response through the gamma-ray and the electron Compton scattering process. However, it is difficult to estimate the systematic uncertainties of those measurements are difficult to assess. In this paper, we used the Geant4 simulation package to study several systematic uncertainties, including the gamma-ray multiple scattering in the detector, the phys. size of the detector and the edging effect. Our simulations shows that all these effects have marginal impact (<1%) on the scintillator energy response measurement. In some applications, this compound(92-71-7)SDS of cas: 92-71-7 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.

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Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 2,5-Diphenyloxazole, is researched, Molecular C15H11NO, CAS is 92-71-7, about Plastic scintillators with efficient light output and pulse shape discrimination produced via photoinitiated polymerization.Safety of 2,5-Diphenyloxazole.

Poly(vinyl toluene) (PVT) overdoped with 2,5-diphenyloxazole and using 1,4-bis(5-phenyloxazol-2-yl)benzene as a fluorescent secondary dopant can be used to detect and differentiate neutron and gamma radiation via scintillation. The low cost of PVT makes these plastic scintillators attractive for both portable and larger sized first line detection of special nuclear materials. Current fabrication methods rely on thermally initiated radical polymerization that generally requires an approx. 5-day heating process in order to produce high quality scintillators. In this work, we report a proof-of-concept photopolymerization process to prepare plastic scintillators up to 20 g in size in 1 day. These plastic scintillators were comparable to standard thermally polymerized samples in terms of their phys. properties and response to various radiation sources. © 2018 Wiley Periodicals, Inc.

In some applications, this compound(92-71-7)Safety of 2,5-Diphenyloxazole is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.

Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

Recommanded Product: 2,5-Diphenyloxazole. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 2,5-Diphenyloxazole, is researched, Molecular C15H11NO, CAS is 92-71-7, about Palladium/copper-catalyzed decarbonylative heteroarylation of amides via C-N bond activation. Author is Zhou, Ping-Xin; Shi, Shuai; Wang, Jia; Zhang, Yalei; Li, Changzheng; Ge, Chunpo.

A novel strategy for the synthesis of 2-arylated oxazole derivatives, e.g., 5-(1-naphthalenyl)-2-phenyloxazole via palladium/copper-catalyzed decarbonylative heteroarylation of amides RC(O)NR1R2 (R = C6H5, 2-FC6H4, 1-naphthyl, etc.; R1R2 = -C(O)(CH2)3C(O)-, -C(O)(CH2)2C(O)-) via C-N bond activation by ground-state destabilization has been reported. This transformation shows good functional group tolerance and delivers the versatile 2-arylated oxazole derivatives in moderate to good yields. This transformation provides unique and efficient strategies for converting readily available amides and the precursor carboxylic acids into valuable chems.

In some applications, this compound(92-71-7)Recommanded Product: 2,5-Diphenyloxazole is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.

Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica

COA of Formula: C15H11NO. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 2,5-Diphenyloxazole, is researched, Molecular C15H11NO, CAS is 92-71-7, about Fluorescent organic particle doped polymer-based gel dosimeter for neutron detection. Author is Bastidas-Bonilla, Karla A.; Podesta-Lerma, Pedro L. M.; Vega-Carrillo, Hector R.; Castaneda-Priego, Ramon; Sarmiento-Gomez, Erick; Gomez-Solis, Christian; Vallejo, Miguel A.; Sosa, Modesto A..

The purpose of this work is to develop a material capable of detecting neutrons produced by photodisintegration in a linear accelerator for its medical use. In this study, we have developed a gel-like material doped with fluorescent organic particles. PPO at 1 wtis used as primary dopant and POPOP as secondary one at 0.03 weight A set of four samples is produced, with boric acid concentrations of 0, 400, 800 and 1200 ppm. The viscoelastic properties of the material are characterized with rheol. measurements, finding a gel-like behavior, i.e., a material that can keep its original shape if no stresses are applied, but can also be deformed by applying a moderate shear rate. Furthermore, the material was irradiated with gamma, electron, and neutron emission sources from 137Cs, 22Na, 60Co, 210Po, 90Sr and 241AmBe, and its response was measured in two different exptl. settings, in two different institutions, for comparative purposes. From these measurements, one can clearly establish that the new material detects neutrons, electrons, and gammas within the MeV regions and below. Thus, our findings show that the developed material and its properties make it a promising technol. for its use in a neutron detector.

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Reference:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica