Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 1424352-59-9, C6H6ClNO2S. A document type is Article, introducing its new discovery., Recommanded Product: 1424352-59-9
An additive-free Pd-catalyzed alpha-allylation of different imino-group-ontaining heterocycles is reported. The activation of alpha-CH pronucleophiles (pKa (DMSO) > 25) occurs without the addition of strong bases or Lewis acids using only the Pd/Xantphos catalyst system. The reaction scope has been studied for various 5- and 6-membered nitrogen-containing heterocycles (yields up to 96%). Mechanistic investigations suggest an initial allylation of the imine-N followed by a Pd-catalyzed formal aza-Claisen rearrangement.
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Reference：
Thiazole | C3H8366NS – PubChem,
Thiazole | chemical compound | Britannica