Silver-Nitrate-Catalyzed N-Arylation of Amines and O-Arylations of Phenols and Alcohols was written by Das, Rima;Mandal, Mrinmay;Chakraborty, Debashis. And the article was included in Asian Journal of Organic Chemistry in 2013.Recommanded Product: 1843-21-6 This article mentions the following:
An efficient and general protocol for an intermol. carbon-nitrogen cross-coupling of amines, alcs., and phenols with halides was developed and the synthesis of the target compounds was achieved using silver nitrate (AgNO3) as a catalyst and N,N-dimethylethylenediamine (N,N-DMEDA) as a ligand and potassium tert-butoxide (KOtBu) as a base under a nitrogen atm. A number of primary, secondary, and heterocyclic amines were coupled with various aryl iodides to give N-aryl derivatives in good to excellent yield. Along with this, several substituted phenols as well as alcs. were coupled with various halides under the same reactions condition to give O-arylated compounds The title compounds thus formed included N-phenylbenzenamine, 1-phenyl-1H-imidazole, 4-phenylmorpholine, 1-phenyl-2,3-indoledione, N-phenylbenzamide, (4-methylphenyl)phenyl ether, (phenoxy)benzene derivatives, methoxybenzene, aryl ethers. In the experiment, the researchers used many compounds, for example, N-Phenylbenzo[d]thiazol-2-amine (cas: 1843-21-6Recommanded Product: 1843-21-6).
N-Phenylbenzo[d]thiazol-2-amine (cas: 1843-21-6) belongs to thiazole derivatives. The thiazole ring is notable as a component of the vitamin thiamine (B1). Various laboratory methods exist for the organic synthesis of thiazoles. Prominent is the Hantzsch thiazole synthesis is a reaction between haloketones and thioamides.Recommanded Product: 1843-21-6
Referemce:
Thiazole | C3H3NS – PubChem,
Thiazole | chemical compound | Britannica